Off the top of my head I remember the German engineer (Oskar Werner); the French chef, Paul Gerard; the two British actors in London; pseudo Canadian Ward Fowler (played by actual Canadian Shatner); Señor Montoya of Mexico; the Ambassador of the fictitious Arab nation; and southerner Tommy Brown.
No matter where they're from, if they commit murder Columbo is waiting to match wits and nab them. Even if he's on vacation and/or on foreign soil. And diplomatic immunity won't stop him.
One thing that's always confused me (and maybe it's meant to be a little unclear) is Emmett Clayton's nationality, which isn't mentioned any more than Tomlin Dudek's (even though you're pretty much meant to assume Dudek is Russian). Clayton is played by very British-sounding Laurence Harvey (yes, I know he was originally from Eastern Europe), but there's that scene where that one American reporter seems in awe of Dudek, and Clayton kids him about not being very patriotic. So that kind of suggests that Clayton himself is meant to be an American. So THE MOST DANGEROUS MATCH is kind of confusing when it comes to nationalities, maybe deliberately.